| 1 | Montanes A. (LL) | Bye | |
| 2 | Kyrgios N. | Brands D. (Q) | 1 : 2 |
| 3 | Pospisil V. | Giraldo S. | 2 : 0 |
| 4 | Bedene A. | Chardy J. (8) | 2 : 1 |
| 5 | Tomic B. (3) | Bye | |
| 6 | Cuevas P. | Carreno-Busta P. | 2 : 0 |
| 7 | Sousa J. | Muller G. | 2 : 0 |
| 8 | Gombos N. (Q) | Paire B. (5) | 1 : 2 |
| 9 | Bautista-Agut R. (7) | Almagro N. (WC) | 2 : 1 |
| 10 | Granollers M. (WC) | Rublev A. (WC) | 0 : 2 |
| 11 | Bellucci T. | Zverev M. (Q) | 1 : 2 |
| 12 | Bye | Fognini F. (4) | |
| 13 | Garcia-Lopez G. (6) | Verdasco F. | 2 : 1 |
| 14 | Przysiezny M. (Q) | Daniel T. (Q) | 1 : 2 |
| 15 | Johnson S. | Klizan M. | 2 : 0 |
| 16 | Bye | Lopez F. (2) |
| 1 | Montanes A. (LL) | Brands D. | 0 : 2 |
| 2 | Pospisil V. | Bedene A. | 2 : 0 |
| 3 | Tomic B. (3) | Cuevas P. | 1 : 2 |
| 4 | Sousa J. | Paire B. (5) | 2 : 1 |
| 5 | Bautista-Agut R. (7) | Rublev A. | 2 : 0 |
| 6 | Zverev M. | Fognini F. (4) | 2 : 0 |
| 7 | Garcia-Lopez G. (6) | Daniel T. | 2 : 0 |
| 8 | Johnson S. | Lopez F. (2) | 2 : 0 |
| 1 | Brands D. | Pospisil V. | 0 : 2 |
| 2 | Cuevas P. | Sousa J. | 0 : 2 |
| 3 | Bautista-Agut R. (7) | Zverev M. | 2 : 0 |
| 4 | Garcia-Lopez G. (6) | Johnson S. | 0 : 2 |
| 1 | Pospisil V. | Sousa J. | 0 : 2 |
| 2 | Bautista-Agut R. (7) | Johnson S. | 2 : 1 |
| 1 | Sousa J. | Bautista-Agut R. (7) | 2 : 1 |
| 1 | Delbonis F. (1) | Zverev M. | 0 : 2 |
| 2 | Vilella M. M. | Martinez P. (WC) | 2 : 1 |
| 3 | Kuhn N. (Q) | Sugita Y. | 0 : 2 |
| 4 | De Schepper K. | Struff J-L. (7) | 0 : 2 |
| 5 | Taberner C. | Correia J. (WC) | 2 : 0 |
| 6 | Przysiezny M. | Marti J. | 2 : 0 |
| 7 | Halys Q. | Roca Batalla O. | 2 : 1 |
| 8 | Hemery C. | Ram R. (5) | 0 : 2 |
| 9 | Kokkinakis T. (3) | Alcaraz Ivorra A. | 2 : 0 |
| 10 | Zapata Miralles B. (WC) | Brands D. | 0 : 2 |
| 11 | Gakhov I. | Kamke T. | 0 : 2 |
| 12 | Metreveli A. | Montanes A. (8) | 0 : 2 |
| 13 | Gimeno-Traver D. (4) | Giner M. | 0 : 2 |
| 14 | Daniel T. | Djere L. (RET.) | 1 : 0 |
| 15 | Checa-Calvo J. (RET.) | Kovalik J. | 0 : 1 |
| 16 | Gombos N. | Cervantes I. (6) | 2 : 0 |
| 1 | Zverev M. | Vilella M. M. | 2 : 0 |
| 2 | Sugita Y. | Struff J-L. (7) | 2 : 1 |
| 3 | Taberner C. | Przysiezny M. | 0 : 2 |
| 4 | Halys Q. | Ram R. (5) | 2 : 0 |
| 5 | Kokkinakis T. (3) | Brands D. | 0 : 2 |
| 6 | Kamke T. | Montanes A. (8) | 1 : 2 |
| 7 | Giner M. | Daniel T. | 0 : 2 |
| 8 | Kovalik J. | Gombos N. | 0 : 2 |
| 1 | Zverev M. | Sugita Y. | 2 : 0 |
| 2 | Przysiezny M. | Halys Q. | 2 : 0 |
| 3 | Brands D. | Montanes A. (8) | 2 : 0 |
| 4 | Daniel T. | Gombos N. | 2 : 0 |
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