| 1 | Carreno-Busta P. (1) | Bye | |
| 2 | Grenier H. | Fognini F. | 1 : 2 |
| 3 | Nardi L. (WC) | Moutet C. | 1 : 2 |
| 4 | Cobolli F. (WC) | Kecmanovic M. (5) | 0 : 2 |
| 5 | Musetti L. (4) | Bye | |
| 6 | Djere L. | Gojo B. (Q) | 2 : 0 |
| 7 | Zapata Miralles B. | Galan D. E. | 0 : 2 |
| 8 | Borges N. | Ramos A. (7) | 2 : 0 |
| 9 | Baez S. (6) | Sonego L. | 2 : 0 |
| 10 | Fucsovics M. | Zhang Z. (Q) | 0 : 2 |
| 11 | McDonald M. | Passaro F. (Q) | 2 : 0 |
| 12 | Bye | Bautista-Agut R. (3) | |
| 13 | Mannarino A. (8) | Cachin P. | 1 : 2 |
| 14 | Daniel T. | Martinez P. | 2 : 0 |
| 15 | Carballes Baena R. | Jarry N. (Q) | 2 : 0 |
| 16 | Bye | Berrettini M. (WC) |
| 1 | Carreno-Busta P. (1) | Fognini F. | 2 : 0 |
| 2 | Moutet C. (RET.) | Kecmanovic M. (5) | 0 : 0 |
| 3 | Musetti L. (4) | Djere L. | 2 : 0 |
| 4 | Galan D. E. | Borges N. | 2 : 0 |
| 5 | Baez S. (6) | Zhang Z. | 0 : 2 |
| 6 | McDonald M. | Bautista-Agut R. (3) | 2 : 0 |
| 7 | Cachin P. | Daniel T. | 0 : 2 |
| 8 | Carballes Baena R. | Berrettini M. (2) | 0 : 2 |
| 1 | Carreno-Busta P. (1) | Kecmanovic M. (5) | 0 : 2 |
| 2 | Musetti L. (4) | Galan D. E. | 2 : 0 |
| 3 | Zhang Z. | McDonald M. | 1 : 2 |
| 4 | Daniel T. | Berrettini M. (2) | 0 : 2 |
| 1 | Kecmanovic M. (5) | Musetti L. (4) | 0 : 2 |
| 2 | McDonald M. | Berrettini M. (2) | 1 : 2 |
| 1 | Musetti L. (4) | Berrettini M. (2) | 2 : 0 |
| 1 | Jarry N. (1) | Dougaz A. | 2 : 0 |
| 2 | Ferrari G. (WC) | Brancaccio R. (8) | 0 : 2 |
| 3 | Zhang Z. (2) | Bonadio R. | 2 : 0 |
| 4 | Zhukayev B. | Zeppieri G. (7) | 0 : 2 |
| 5 | Passaro F. (3) | Giustino L. | 2 : 1 |
| 6 | Maestrelli F. | Misolic F. (5) | 0 : 2 |
| 7 | Kovalik J. (RET.) (4) | Gojo B. | 0 : 1 |
| 8 | Napolitano S. (WC) | Pellegrino A. (6) | 2 : 0 |
| 1 | Jarry N. (1) | Brancaccio R. (8) | 2 : 0 |
| 2 | Zhang Z. (2) | Zeppieri G. (7) | 2 : 1 |
| 3 | Passaro F. (3) | Misolic F. (5) | 2 : 1 |
| 4 | Gojo B. | Napolitano S. | 2 : 0 |
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