| 1 | Alcaraz C. (1) | Rinderknech A. | 2 : 0 |
| 2 | Royer V. | Herbert P. (Q) | 2 : 0 |
| 3 | Fucsovics M. | Habib H. (WC) | 2 : 0 |
| 4 | Mochizuki S. | Khachanov K. (7) | 1 : 2 |
| 5 | Medvedev D. (4) | Shang J. (PR) | 2 : 0 |
| 6 | Echargui M. (WC) | Tsitsipas S. | 0 : 2 |
| 7 | Humbert U. | Marozsan F. | 0 : 2 |
| 8 | De Jong J. | Rublev A. (5) | 0 : 2 |
| 9 | Lehecka J. (8) | Brooksby J. | 2 : 0 |
| 10 | Bergs Z. | Mpetshi Perricard G. | 2 : 1 |
| 11 | Fils A. | Majchrzak K. | 2 : 1 |
| 12 | Carreno-Busta P. (Q) | Halys Q. (LL) | 1 : 2 |
| 13 | Mensik J. (6) | Choinski J. (Q) | 2 : 1 |
| 14 | Zhang Z. (PR) | Carballes Baena R. (Q) | 2 : 0 |
| 15 | Zayid M. S. (WC) | Popyrin A. | 0 : 2 |
| 16 | Machac T. | Sinner J. (2) | 0 : 2 |
| 1 | Alcaraz C. (1) | Royer V. | 2 : 0 |
| 2 | Fucsovics M. | Khachanov K. (7) | 1 : 2 |
| 3 | Medvedev D. (4) | Tsitsipas S. | 0 : 2 |
| 4 | Marozsan F. | Rublev A. (5) | 0 : 2 |
| 5 | Lehecka J. (8) | Bergs Z. | 2 : 0 |
| 6 | Fils A. | Halys Q. | 2 : 0 |
| 7 | Mensik J. (6) | Zhang Z. | 2 : 0 |
| 8 | Popyrin A. | Sinner J. (2) | 0 : 2 |
| 1 | Alcaraz C. (1) | Khachanov K. (7) | 2 : 1 |
| 2 | Tsitsipas S. | Rublev A. (5) | 0 : 2 |
| 3 | Lehecka J. (8) | Fils A. | 0 : 2 |
| 4 | Mensik J. (6) | Sinner J. (2) | 2 : 1 |
| 1 | Alcaraz C. (1) | Rublev A. (5) | 2 : 0 |
| 2 | Fils A. | Mensik J. (6) | 2 : 0 |
| 1 | Alcaraz C. (1) | Fils A. | 2 : 0 |
| 1 | Halys Q. (1) | Alkaya M. (WC) | 2 : 0 |
| 2 | McCabe J. | Choinski J. (7) | 0 : 2 |
| 3 | Vukic A. (2) | Herbert P. | 0 : 2 |
| 4 | Basilashvili N. (RET.) | Ymer E. (Alt) | 0 : 1 |
| 5 | Carreno-Busta P. (3) | Bennani R. (WC) | 2 : 0 |
| 6 | Trungelliti M. | Harris B. (8) | 1 : 2 |
| 7 | Mochizuki S. (4) | Al-Sulaiti G. (WC) | 2 : 0 |
| 8 | Carballes Baena R. | Miedler L. (Alt) | 2 : 0 |
| 1 | Halys Q. (1) | Choinski J. (7) | 1 : 2 |
| 2 | Herbert P. | Ymer E. | 2 : 1 |
| 3 | Carreno-Busta P. (3) | Harris B. (8) | 2 : 0 |
| 4 | Mochizuki S. (4) | Carballes Baena R. | 0 : 2 |
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