| 1 | Zverev A. (1) | Kecmanovic M. | 2 : 1 |
| 2 | Diallo G. | Sachko V. (Q) | 2 : 0 |
| 3 | Van De Zandschulp B. | Huesler M. (Q) | 2 : 0 |
| 4 | Nagal S. (LL) | Cerundolo F. (5) | 0 : 2 |
| 5 | Cobolli F. (4) | Dedura D. (Q) | 2 : 0 |
| 6 | Bergs Z. | Topo M. (LL) | 2 : 0 |
| 7 | Engel J. (WC) | Kopriva V. | 1 : 2 |
| 8 | Zhang Z. (PR) | Darderi L. (6) | 1 : 2 |
| 9 | Griekspoor T. (8) | Shapovalov D. | 1 : 2 |
| 10 | Marozsan F. | Tsitsipas S. | 2 : 1 |
| 11 | Cilic M. | Altmaier D. | 0 : 2 |
| 12 | Molcan A. (Q) | Bublik A. (3) | 2 : 0 |
| 13 | Rinderknech A. (7) | Michelsen A. | 2 : 0 |
| 14 | Tabilo A. | Fonseca J. | 0 : 2 |
| 15 | Blockx A. (WC) | Hanfmann Y. | 2 : 0 |
| 16 | Nava E. (LL) | Shelton B. (2) | 1 : 2 |
| 1 | Zverev A. (1) | Diallo G. | 2 : 0 |
| 2 | Van De Zandschulp B. | Cerundolo F. (5) | 0 : 2 |
| 3 | Cobolli F. (4) | Bergs Z. | 2 : 0 |
| 4 | Kopriva V. | Darderi L. (6) | 2 : 1 |
| 5 | Shapovalov D. | Marozsan F. | 2 : 0 |
| 6 | Altmaier D. | Molcan A. | 0 : 2 |
| 7 | Rinderknech A. (7) | Fonseca J. | 0 : 2 |
| 8 | Blockx A. | Shelton B. (2) | 0 : 2 |
| 1 | Zverev A. (1) | Cerundolo F. (5) | 2 : 1 |
| 2 | Cobolli F. (4) | Kopriva V. | 2 : 0 |
| 3 | Shapovalov D. | Molcan A. | 0 : 2 |
| 4 | Fonseca J. | Shelton B. (2) | 1 : 2 |
| 1 | Zverev A. (1) | Cobolli F. (4) | 0 : 2 |
| 2 | Molcan A. | Shelton B. (2) | 0 : 2 |
| 1 | Cobolli F. (4) | Shelton B. (2) | 0 : 2 |
| 1 | Shevchenko A. (1) | Dedura D. (WC) | 0 : 2 |
| 2 | Giustino L. (RET.) | Nagal S. (Alt) | 1 : 1 |
| 3 | Dzumhur D. (2) | Sachko V. | 0 : 2 |
| 4 | Rehberg M. H. (WC) | Fery A. (8) | 2 : 0 |
| 5 | Nava E. (3) | Goffin D. | 2 : 0 |
| 6 | Carballes Baena R. | Molcan A. (7) | 1 : 2 |
| 7 | Choinski J. (4) | Huesler M. | 1 : 2 |
| 8 | Topo M. (WC) | Blanchet U. (6) | 2 : 0 |
| 1 | Dedura D. | Nagal S. | 2 : 1 |
| 2 | Sachko V. | Rehberg M. H. | 2 : 0 |
| 3 | Nava E. (3) | Molcan A. (7) | 0 : 2 |
| 4 | Huesler M. | Topo M. | 2 : 0 |
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