| 1 | Zverev A. (1) | Bye | |
| 2 | Walton A. | Bonzi B. | 2 : 1 |
| 3 | Schoolkate T. (Q) | Fonseca J. | 2 : 0 |
| 4 | Bye | Arnaldi M. (32) | |
| 5 | Griekspoor T. (24) | Bye | |
| 6 | Herbert P. (Q) | Etcheverry T. M. | 1 : 2 |
| 7 | Martin D. (Q) | Munar J. | 0 : 2 |
| 8 | Bye | Cerundolo F. (14) | |
| 9 | Medvedev D. (10) | Bye | |
| 10 | Blockx A. (Q) | Svrcina D. (LL) | 0 : 2 |
| 11 | Arseneault N. (WC) | Royer V. (Q) | 2 : 0 |
| 12 | Bye | Popyrin A. (18) | |
| 13 | Muller A. (29) | Bye | |
| 14 | Kecmanovic M. | Halys Q. | 2 : 1 |
| 15 | Mochizuki S. (Q) | Mpetshi Perricard G. | 0 : 2 |
| 16 | Bye | Rune H. (5) | |
| 17 | Musetti L. (3) | Bye | |
| 18 | Shang J. | Duckworth J. (Q) | 0 : 2 |
| 19 | Monfils G. | Barrios Vera T. (Q) | 1 : 2 |
| 20 | Bye | Michelsen A. (26) | |
| 21 | Shapovalov D. (22) | Bye | |
| 22 | Smith C. (Q) | Tien L. | 0 : 2 |
| 23 | Ofner S. (PR) | Opelka R. | 0 : 2 |
| 24 | Bye | Machac T. (16) | |
| 25 | Khachanov K. (11) | Bye | |
| 26 | Fearnley J. | Ficovich J. P. (Q) | 0 : 2 |
| 27 | Nava E. (Q) | Bergs Z. | 2 : 0 |
| 28 | Bye | Atmane T. (LL) | |
| 29 | Borges N. (30) | Bye | |
| 30 | Bagnis F. (Q) | Pospisil V. (WC) | 2 : 1 |
| 31 | Safiullin R. | Blanchet U. (Q) | 2 : 1 |
| 32 | Bye | Ruud C. (8) | |
| 33 | Tiafoe F. (7) | Bye | |
| 34 | Watanuki Y. (Q) | Altmaier D. | 2 : 1 |
| 35 | Vukic A. | Martinez P. | 2 : 0 |
| 36 | Bye | Norrie C. (31) | |
| 37 | Tsitsipas S. (23) | Bye | |
| 38 | O'Connell C. | Tseng C. H. (LL) | 2 : 0 |
| 39 | Comesana F. | Dzumhur D. | 2 : 0 |
| 40 | Bye | De Minaur A. (9) | |
| 41 | Cobolli F. (13) | Bye | |
| 42 | Rinderknech A. | Galarneau A. (WC) | 0 : 2 |
| 43 | Marozsan F. | Dellien H. | 2 : 0 |
| 44 | Bye | Auger-Aliassime F. (21) | |
| 45 | Nakashima B. (25) | Bye | |
| 46 | Quinn E. | Nishioka Y. | 2 : 0 |
| 47 | Giron M. | Mannarino A. (Q) | 0 : 2 |
| 48 | Bye | Shelton B. (4) | |
| 49 | Rublev A. (6) | Bye | |
| 50 | Bellucci M. (RET.) | Gaston H. | 1 : 1 |
| 51 | Kopriva V. | Bu Y. | 0 : 2 |
| 52 | Bye | Sonego L. (28) | |
| 53 | Davidovich Fokina A. (20) | Bye | |
| 54 | Moutet C. | Brooksby J. (PR) | 2 : 0 |
| 55 | Boyer T. (Q) | Kovacevic A. | 2 : 0 |
| 56 | Bye | Mensik J. (12) | |
| 57 | Fils A. (15) | Bye | |
| 58 | Draxl L. (WC) | Carreno-Busta P. | 1 : 2 |
| 59 | McDonald M. | Goffin D. | 2 : 0 |
| 60 | Bye | Lehecka J. (19) | |
| 61 | Diallo G. (27) | Bye | |
| 62 | Coric B. | Gigante M. (WC) | 1 : 2 |
| 63 | Carballes Baena R. | Ugo Carabelli C. (RET.) | 1 : 0 |
| 64 | Bye | Fritz T. (2) |
| 1 | Zverev A. (1) | Walton A. | 2 : 0 |
| 2 | Schoolkate T. | Arnaldi M. (32) | 1 : 2 |
| 3 | Griekspoor T. (24) | Etcheverry T. M. | 0 : 2 |
| 4 | Munar J. | Cerundolo F. (14) | 1 : 2 |
| 5 | Medvedev D. (10) | Svrcina D. | 2 : 0 |
| 6 | Arseneault N. | Popyrin A. (18) | 0 : 2 |
| 7 | Muller A. (29) | Kecmanovic M. | 2 : 1 |
| 8 | Mpetshi Perricard G. | Rune H. (5) | 0 : 2 |
| 9 | Musetti L. (3) | Duckworth J. | 2 : 0 |
| 10 | Barrios Vera T. | Michelsen A. (26) | 0 : 2 |
| 11 | Shapovalov D. (22) | Tien L. | 0 : 2 |
| 12 | Opelka R. | Machac T. (16) | 2 : 1 |
| 13 | Khachanov K. (11) | Ficovich J. P. | 2 : 0 |
| 14 | Nava E. | Atmane T. | 2 : 0 |
| 15 | Borges N. (30) | Bagnis F. | 2 : 1 |
| 16 | Safiullin R. | Ruud C. (8) | 0 : 2 |
| 17 | Tiafoe F. (7) | Watanuki Y. | 2 : 1 |
| 18 | Vukic A. | Norrie C. (31) | 2 : 1 |
| 19 | Tsitsipas S. (23) | O'Connell C. | 1 : 2 |
| 20 | Comesana F. | De Minaur A. (9) | 0 : 2 |
| 21 | Cobolli F. (13) | Galarneau A. | 2 : 1 |
| 22 | Marozsan F. | Auger-Aliassime F. (21) | 2 : 0 |
| 23 | Nakashima B. (25) | Quinn E. | 2 : 0 |
| 24 | Mannarino A. | Shelton B. (4) | 0 : 2 |
| 25 | Rublev A. (6) | Gaston H. | 2 : 0 |
| 26 | Bu Y. | Sonego L. (28) | 0 : 2 |
| 27 | Davidovich Fokina A. (20) | Moutet C. | 2 : 0 |
| 28 | Boyer T. | Mensik J. (12) | 0 : 2 |
| 29 | Fils A. (15) | Carreno-Busta P. | 2 : 0 |
| 30 | McDonald M. | Lehecka J. (19) | 0 : 2 |
| 31 | Diallo G. (27) | Gigante M. | 2 : 0 |
| 32 | Carballes Baena R. | Fritz T. (2) | 0 : 2 |
| 1 | Zverev A. (1) | Arnaldi M. (32) | 2 : 1 |
| 2 | Etcheverry T. M. | Cerundolo F. (14) | 0 : 2 |
| 3 | Medvedev D. (10) | Popyrin A. (18) | 1 : 2 |
| 4 | Muller A. (29) | Rune H. (5) | 0 : 2 |
| 5 | Musetti L. (3) | Michelsen A. (26) | 1 : 2 |
| 6 | Tien L. | Opelka R. | 2 : 0 |
| 7 | Khachanov K. (11) | Nava E. | 2 : 1 |
| 8 | Borges N. (30) | Ruud C. (8) | 0 : 2 |
| 9 | Tiafoe F. (7) | Vukic A. | 2 : 1 |
| 10 | O'Connell C. | De Minaur A. (WO.) (9) | |
| 11 | Cobolli F. (13) | Marozsan F. | 2 : 1 |
| 12 | Nakashima B. (25) | Shelton B. (4) | 1 : 2 |
| 13 | Rublev A. (6) | Sonego L. (28) | 2 : 1 |
| 14 | Davidovich Fokina A. (20) | Mensik J. (12) | 2 : 0 |
| 15 | Fils A. (15) | Lehecka J. (19) | 1 : 2 |
| 16 | Diallo G. (27) | Fritz T. (2) | 0 : 2 |
| 1 | Zverev A. (1) | Cerundolo F. (RET.) (14) | 1 : 0 |
| 2 | Popyrin A. (18) | Rune H. (5) | 2 : 1 |
| 3 | Michelsen A. (26) | Tien L. | 2 : 0 |
| 4 | Khachanov K. (11) | Ruud C. (8) | 2 : 0 |
| 5 | Tiafoe F. (7) | De Minaur A. (9) | 1 : 2 |
| 6 | Cobolli F. (13) | Shelton B. (4) | 1 : 2 |
| 7 | Rublev A. (6) | Davidovich Fokina A. (RET.) (20) | 1 : 1 |
| 8 | Lehecka J. (19) | Fritz T. (2) | 1 : 2 |
| 1 | Zverev A. (1) | Popyrin A. (18) | 2 : 1 |
| 2 | Michelsen A. (26) | Khachanov K. (11) | 0 : 2 |
| 3 | De Minaur A. (9) | Shelton B. (4) | 0 : 2 |
| 4 | Rublev A. (6) | Fritz T. (2) | 0 : 2 |
| 1 | Zverev A. (1) | Khachanov K. (11) | 1 : 2 |
| 2 | Shelton B. (4) | Fritz T. (2) | 2 : 0 |
| 1 | Khachanov K. (11) | Shelton B. (4) | 1 : 2 |
| 1 | Mannarino A. (1) | Aguilar J. C. M. (28) | 2 : 0 |
| 2 | Tseng C. H. (2) | Blanchet U. (24) | 0 : 2 |
| 3 | Schoolkate T. (3) | Nanda G. (27) | 2 : 0 |
| 4 | Duckworth J. (4) | Boulais J. (31) | 2 : 0 |
| 5 | Royer V. (5) | Tudorica A. N. (29) | 2 : 0 |
| 6 | Nava E. (6) | Krueger M. (19) | 2 : 0 |
| 7 | Svrcina D. (7) | Watanuki Y. (17) | 1 : 2 |
| 8 | Blockx A. (8) | Ajdukovic D. (26) | 2 : 0 |
| 9 | Mochizuki S. (9) | Uchiyama Y. (25) | 2 : 0 |
| 10 | Boyer T. (10) | Trotter J. K. (22) | 2 : 0 |
| 11 | Atmane T. (11) | Bagnis F. (32) | 0 : 2 |
| 12 | Ficovich J. P. (12) | Jacquet K. (18) | 2 : 1 |
| 13 | Smith C. (13) | Kypson P. (23) | 2 : 0 |
| 14 | Herbert P. (14) | Tu L. (20) | 2 : 1 |
| 15 | Barrios Vera T. (15) | Wong C. (21) | 2 : 0 |
| 16 | Daniel T. (16) | Martin D. (30) | 1 : 2 |
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